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Acetylacetonatocarbonyltriphenylphosphine rhodium CAS: 25470-96-6

Short Description:

Catalog Number: XD93991
Cas: 25470-96-6
Molecular Formula: C24H23O3PRh
Molecular Weight: 493.32
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Product Detail

Product Tags

Catalog Number XD93991
Product Name Acetylacetonatocarbonyltriphenylphosphine rhodium
CAS 25470-96-6
Molecular Formula C24H23O3PRh
Molecular Weight 493.32
Storage Details Ambient

 

Product Specification

Appearance White powder
Assay 99% min

 

Acetylacetonatocarbonyltriphenylphosphine rhodium (Rh(acac)(CO)(PPh3)) is a rhodium complex that consists of a rhodium center coordinated to an acetylacetonate ligand (acac), a carbonyl ligand (CO), and a triphenylphosphine ligand (PPh3). This complex is extensively used as a catalyst in various organic synthesis reactions.One of the primary applications of Acetylacetonatocarbonyltriphenylphosphine rhodium is in the hydroformylation reaction, also known as the oxo process. Hydroformylation involves the addition of carbon monoxide and hydrogen to an olefin, yielding an aldehyde. The presence of the acetylacetonate ligand in the complex helps stabilize the transition state, improving the efficiency of the reaction. The triphenylphosphine ligand enhances the solubility of the catalyst in organic solvents and aids in controlling the regioselectivity of the hydroformylation reaction. This process is crucial in the production of aldehydes, which are widely used in the manufacture of plastics, solvents, and detergents.Another significant use of Acetylacetonatocarbonyltriphenylphosphine rhodium is in the catalytic hydrogenation of functional groups such as carbon-carbon double bonds and carbonyl groups. The complex acts as a versatile catalyst for these transformations, offering selectivity, high catalytic activity, and excellent functional group tolerance. It finds applications in the synthesis of pharmaceuticals, natural products, and fine chemicals.Additionally, the Acetylacetonatocarbonyltriphenylphosphine rhodium complex is employed in various carbon-heteroatom bond formation reactions. It has been utilized in the synthesis of carbon-silicon, carbon-phosphorus, and carbon-nitrogen bonds. These transformations are important in medicinal chemistry and the preparation of organometallic compounds for use in catalysis.The stability and solubility of Acetylacetonatocarbonyltriphenylphosphine rhodium make it suitable for homogeneous catalysis, where the catalyst and reactants are present in the same phase. It exhibits excellent functional group compatibility and can be easily separated from the reaction mixture after completion of the reaction.Furthermore, Acetylacetonatocarbonyltriphenylphosphine rhodium complexes have been investigated for their luminescent properties. These complexes exhibit unique emission properties and have research applications in materials science and optoelectronics.In summary, Acetylacetonatocarbonyltriphenylphosphine rhodium is a versatile catalyst used in various organic synthesis reactions. Its applications in hydroformylation, hydrogenation, carbon-heteroatom bond formation, and luminescent materials make it a crucial tool in the fields of organic chemistry, materials science, and catalysis research.


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    Acetylacetonatocarbonyltriphenylphosphine rhodium CAS: 25470-96-6