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Tris(dibenzylideneacetone)dipalladium(0) is an important zero-valent palladium catalyst, which is widely used in reactions such as coupling, hydrogenation, and carbonylation in organic synthesis. Used in combination with different ligands, it forms in situ a highly catalytically active zero-valent palladium active material, which is widely used in carbon-carbon bond and carbon-heteroatom bond formation reactions.

As a catalyst, it is used in coupling reactions of Suzuki, Kumada, Negishi, Buchwald, etc. Tris(dibenzylideneacetone)dipalladium is used to prepare semiconducting polymers, which are processed from non-chlorinated solvents into high-performance thin-film transistors. Also used in the synthesis of polymer bulk heterojunction solar cells as semiconductors.

Aryl chloride Suzuki coupling reaction catalyst; Aryl chloride Heck coupling reaction catalyst; Ketone arylation reaction catalyst; Aryl halide Buchwald-Hartwig amination reaction catalyst; Allyl chloride fluorination reaction catalyst; Carboxyl Catalysts for the β-arylation of esters; catalysts for the carbonylation of 1,1-dichloro-1-alkenes; catalysts for the conversion of aryl and vinyl triflates to aryl and vinyl halides.